The effect of indium(III) triflate in oxone-mediated oxidative methyl esterification of aldehydes.
Identifieur interne : 000331 ( Main/Exploration ); précédent : 000330; suivant : 000332The effect of indium(III) triflate in oxone-mediated oxidative methyl esterification of aldehydes.
Auteurs : RBID : pubmed:23902869English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Aldehydes, Hydrocarbons, Aromatic, Mesylates, Sulfuric Acids.
- Esterification, Methylation, Oxidation-Reduction.
Abstract
An oxidative methyl esterification of aldehydes was effectively achieved. The trivalent indium reagent, indium(III) triflate, was revealed to accelerate the reactions in many cases. Aromatic aldehydes with various substituents were subjected to this method, and each produced the corresponding methyl esters in good to excellent yields within a relatively short reaction time.
PubMed: 23902869
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The trivalent indium reagent, indium(III) triflate, was revealed to accelerate the reactions in many cases. Aromatic aldehydes with various substituents were subjected to this method, and each produced the corresponding methyl esters in good to excellent yields within a relatively short reaction time.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">23902869</PMID><DateCreated><Year>2013</Year><Month>08</Month><Day>01</Day></DateCreated><DateCompleted><Year>2014</Year><Month>02</Month><Day>18</Day></DateCompleted><Article PubModel="Print"><Journal><ISSN IssnType="Electronic">1347-5223</ISSN><JournalIssue CitedMedium="Internet"><Volume>61</Volume><Issue>8</Issue><PubDate><Year>2013</Year></PubDate></JournalIssue><Title>Chemical & pharmaceutical bulletin</Title><ISOAbbreviation>Chem. Pharm. 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Aromatic aldehydes with various substituents were subjected to this method, and each produced the corresponding methyl esters in good to excellent yields within a relatively short reaction time.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Mineno</LastName><ForeName>Tomoko</ForeName><Initials>T</Initials><Affiliation>Laboratory of Medicinal Chemistry, Faculty of Pharmacy, Takasaki University of Health and Welfare, 60 Nakaorui, Takasaki, Gunma 370–0033, Japan.</Affiliation></Author><Author ValidYN="Y"><LastName>Sakai</LastName><ForeName>Mai</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Ubukata</LastName><ForeName>Akira</ForeName><Initials>A</Initials></Author><Author ValidYN="Y"><LastName>Nakahara</LastName><ForeName>Kazuhide</ForeName><Initials>K</Initials></Author><Author ValidYN="Y"><LastName>Yoshimitsu</LastName><ForeName>Hitoshi</ForeName><Initials>H</Initials></Author><Author ValidYN="Y"><LastName>Kansui</LastName><ForeName>Hisao</ForeName><Initials>H</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType><PublicationType>Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>Japan</Country><MedlineTA>Chem Pharm Bull (Tokyo)</MedlineTA><NlmUniqueID>0377775</NlmUniqueID><ISSNLinking>0009-2363</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Aldehydes</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Hydrocarbons, Aromatic</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Mesylates</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Sulfuric Acids</NameOfSubstance></Chemical><Chemical><RegistryNumber>HL6A2XXU5D</RegistryNumber><NameOfSubstance>potassium peroxymonosulfuric acid</NameOfSubstance></Chemical><Chemical><RegistryNumber>JE2SY203E8</RegistryNumber><NameOfSubstance>trifluoromethanesulfonic acid</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N">Aldehydes</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Esterification</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Hydrocarbons, Aromatic</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Mesylates</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Methylation</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Oxidation-Reduction</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Sulfuric Acids</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2013</Year><Month>8</Month><Day>2</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2013</Year><Month>8</Month><Day>2</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2014</Year><Month>2</Month><Day>19</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pii">DN/JST.JSTAGE/cpb/c13-00072</ArticleId><ArticleId IdType="pubmed">23902869</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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